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Photoinitiator Co-Sensitizer Valerophenone CAS 1009-14-9 UV Curing Grade Liquid

Basic Properties
Place of Origin: China
Brand Name: Senzhuo
Certification: ISO9001
Model Number: SZ-VP-03
Trading Properties
Minimum Order Quantity: 1kg
Price: US $120 - 160/ kg
Payment Terms: T/T, Western Union, L/C
Supply Ability: 100 tons per month
Product Summary
In UV curing, aromatic ketones work as hydrogen abstractors: after absorbing light they pull a hydrogen atom from a co initiator or from the resin backbone and generate the radicals that start polymerisation. Valerophenone (CAS 1009-14-9) is used in that role because its absorption and triplet ...

Product Details

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photoinitiator co-sensitizer

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UV curing ketone

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valerophenone UV grade

Product Name: Valerophenone
CAS: 1009-14-9
MF: C11H14O
MW: 162.23
Grade: UV Curing Grade
Assay: 99.5% Min
Application: Photoinitiator Co-sensitizer
Product Description

In UV curing, aromatic ketones work as hydrogen abstractors: after absorbing light they pull a hydrogen atom from a co initiator or from the resin backbone and generate the radicals that start polymerisation. Valerophenone (CAS 1009-14-9) is used in that role because its absorption and triplet behaviour sit in a useful window, its fragmentation products are low odour compared with the classic amines, and it stays in the film rather than evaporating at the lamp.

For a coating formulator, the practical result is faster surface cure and a harder, less tacky film at the same lamp dose, particularly in acrylate systems where oxygen inhibition otherwise leaves a soft surface. This grade is specified for water, acidity and colour, since each of those either quenches the excited state or yellows the cured film, and it is packed in amber glass or nitrogen blanketed drums to keep the specification intact.

Key Features
  • Efficient hydrogen abstraction: faster surface cure and reduced tack in acrylate coatings and inks
  • Works as co initiator with benzophenone: lower total photoinitiator load for the same cure speed
  • Low odour compared with amine synergists: suitable for packaging and interior coating applications
  • Colour 20 APHA maximum: no yellowing contribution in clear coats and light coloured inks
  • Water 0.1% maximum: no haze in solvent borne and 100% solids UV systems
  • Non volatile at process temperature: stays in the film during drying, so the cure response is predictable
Technical Specifications
ParameterSpecification
Product NameValerophenone (n-Butyl Phenyl Ketone)
CAS Number1009-14-9
Molecular FormulaC11H14O
Molecular Weight162.23 g/mol
EINECS213-767-3
HS Code29143900
GradeUV curing and photochemical grade
Assay (GC)99.5% minimum
Water Content0.10% maximum
Acid Value0.05 mg KOH/g maximum
AppearanceColourless clear liquid
Colour (APHA)20 maximum
UV Absorbance MaximumReported per lot (methanol)
Recommended Dosage1 to 4% on resin solids
Boiling Point244 to 245 degrees C
Density (20 degrees C)0.974 to 0.978 g/mL
Storage5-25 degrees C, amber or opaque container
Shelf Life24 months in unopened packaging
Applications and Handling Notes

Used as a photoinitiator or co sensitizer in UV curable coatings, flexographic and offset inks, adhesives and 3D printing resins, usually at 1 to 4 percent on resin solids alongside a benzophenone or thioxanthone primary initiator.

Because cure response depends on lamp spectrum and on the resin, we recommend a dosage ladder of 1, 2 and 3 percent tested at the production lamp dose, measuring surface tack, pendulum hardness and adhesion. Our technical note includes cure speed data against dosage in a standard epoxy acrylate and a urethane acrylate system.

Packaging, Storage and Transport

Packed in 1 kg amber glass bottles for formulation trials, 25 kg plastic drums and 200 kg iron drums for production, nitrogen blanketed where the container will be stored for long periods. Labels record lot number, assay, UV absorbance and production date.

Store between 5 and 25 degrees C in an opaque or amber container away from light and oxidisers; the product should not be left in clear glass on a sunlit bench. Shipments leave within 7 to 15 working days with COA, TDS and safety data sheet.

Quality Assurance and Documentation

Each lot is released with a Certificate of Analysis reporting assay, water, acid value, colour, UV absorbance maximum and density, plus the GC chromatogram. A 200 g retention sample is kept for 24 months.

We provide a GHS safety data sheet, a UV cure data sheet comparing dosage against surface cure and hardness, and a declaration of SVHC content. Custom blends with benzophenone or amine synergists can be quoted for volume programmes.

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