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Catalyst Precursor MMT CAS 12108-13-3 Low Halide Manganese Source Grade

Basic Properties
Place of Origin: China
Brand Name: Senzhuo
Certification: ISO9001
Model Number: SZ-MM-03
Trading Properties
Minimum Order Quantity: 5kg
Price: US $60 - 80/ kg
Payment Terms: T/T, Western Union, L/C
Supply Ability: 8 tons per month
Product Summary
When MMT is used to put manganese into a catalyst or a thin film, halide is the impurity that shows up later as corrosion or as a poisoning effect on the active site. Our catalyst precursor grade is made with a halide control step and tested by ion chromatography, so the chloride and bromide figures ...

Product Details

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MMT catalyst precursor

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manganese carbonyl source

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low halide 12108-13-3

Product Name: MMT
CAS: 12108-13-3
MF: C9H7MnO3
MW: 218.09
Grade: Catalyst Precursor
Halide: 15 Ppm Max
Mn: 25.0-25.4%
Product Description

When MMT is used to put manganese into a catalyst or a thin film, halide is the impurity that shows up later as corrosion or as a poisoning effect on the active site. Our catalyst precursor grade is made with a halide control step and tested by ion chromatography, so the chloride and bromide figures are measured rather than assumed.

The material is also filtered before filling, which matters for chemical vapour deposition and for spin coating, where a particle becomes a defect. Assay is 99% with manganese at the standard 25%, and the packaging is nitrogen padded so the material does not oxidise between the plant and the customer's glovebox.

Key Features
  • Halide under 15 ppm total: no chloride poisoning of the active site and no corrosion of the deposition hardware
  • Filtered before filling: no particles to become defects in a film or a coating
  • Manganese content reported: the figure needed for the stoichiometry of the downstream step
  • Nitrogen padded cans: no oxidation during storage between campaigns
  • Consistent vaporisation behaviour: stable precursor flow in CVD and MOCVD work
  • 5 kg to 25 kg: pilot volumes without buying a drum
Technical Specifications
ParameterSpecification
Product NameMethylcyclopentadienyl Manganese Tricarbonyl (MMT)
CAS Number12108-13-3
Molecular FormulaC9H7MnO3
Molecular Weight218.09 g/mol
EINECS235-166-5
HS Code29319000
GradeCatalyst precursor
Assay (GC)99.0% minimum
Total Halide (Cl plus Br)15 ppm maximum
Iron Content15 ppm maximum
Manganese Content25.0 to 25.4% by weight
Particles above 1 micronReported per lot
AppearanceOrange clear liquid
Water Content0.05% maximum
Density (20 degrees C)1.37 to 1.39 g/mL
StorageBelow 25 degrees C, sealed under nitrogen, dark
Shelf Life18 months in unopened packaging
Where It Is Used

Preparation of manganese containing catalysts, deposition of manganese oxide films by CVD or spray pyrolysis, and as a liquid precursor where a volatile organometallic is easier to meter than a solid salt.

Meter by liquid flow controller rather than by bubbling, since the vapour pressure is low at room temperature. Keep the precursor at a stable temperature in the delivery vessel; a few degrees of drift changes the dose and shows up as a thickness variation across the wafer or the coated part.

Packing, Storage and Transport

5 kg lined can, 25 kg lined steel pail and 200 kg drum on request, all nitrogen padded and filtered at filling. Labels record the halide result and the filtration step.

Store below 25 degrees C, sealed under nitrogen, in the dark. Air freight for cans, sea freight for pails and drums.

Analysis and Paperwork

COA with assay, manganese, total halide by ion chromatography, iron, water, particles and density, plus the GC trace. A 100 g retention sample per lot is kept for 18 months.

Ion chromatography report and a particle count report are available for deposition customers. We can quote a tighter halide limit if the process is sensitive below 10 ppm.

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